Pictured: (l-r) Julie White as Anne, Piper Perabo as Simone -- (Photo by: Justin Lubin/NBC) Photo

From: Photo Flash: First Look - GO ON's 'Double Down,' Airing 3/5

On next week's all new episode of GO ON, titled 'Double Down,' Ryan (Matthew Perry), still pained from the breakup with Simone, (Piper Perabo) backslides into his old gambling habit, though sternly warned by Lauren (Laura Benanti) to steer clear. But when he receives the life insurance check for his deceased wife, it's more than he can bear and he starts making bets on anything and everything. Meanwhile Anne (Julie White) meets a stunning, young bookstore clerk, Brittney, (Annie Heise) who turns out to be all beauty and no brains. Lauren comes to Ryan's rescue by fleecing him at poker and in the aftermath, Ryan bonds with Anne over their respective lost loves. 'Double Down' airs March 5 at 9 p.m. on NBC.